Authenticating Malachite: Formation, Testing & Quality
Geography & Geological Formation of Malachite
Malachite's distinct green colouring is intimately tied to its geological formation processes and the diverse geographical locations where it is found.
GEOLOGICAL FORMATION
Malachite is a secondary mineral that forms through the chemical alteration of minerals containing copper, primarily in the upper oxidation zones of copper deposits. This alteration process is influenced by water and carbon dioxide from the surrounding environment. As water seeps through copper-bearing rocks, it reacts with copper sulphide minerals to form new compounds, including copper carbonates such as malachite. In simpler terms, malachite forms when water interacts with copper inside rocks, leading to a reaction that creates this green gemstone.
The formation of malachite is greatly influenced by the local environmental conditions, particularly the presence of water and carbon dioxide. This dependency means that any changes in these factors can affect the quality and quantity of malachite formation. For instance, areas with higher levels of groundwater or more intense seasonal rains may facilitate more substantial malachite growth. Basically, the more water and carbon dioxide in an area, the better the conditions for forming malachite. This is why environmental factors are crucial in determining where and how well malachite can form.
Malachite is commonly found in the oxidised zones of copper mining areas, where copper ores are exposed to oxygen-rich environments. These zones are often located near the surface where weathering processes are most active, aiding the formation of malachite through the breakdown of primary copper minerals like chalcopyrite and bornite. This means malachite usually forms near the Earth's surface where copper in rocks reacts with oxygen and water.
DEMOCRATIC REPUBLIC OF (DRC)
The Copperbelt in the DRC is one of the most prolific copper-producing areas in the world and is renowned for its extensive malachite deposits. The high-quality malachite from this region is characterised by its rich, vibrant green colours and intricate banding patterns.
AUSTRALIA AND NAMIBIA
Both countries host significant deposits of malachite, particularly in regions with past volcanic activity and current semi-arid conditions, which promote the formation of this mineral.
These locations are notable for their copper deposits, which is essential for malachite formation. The presence of copper, along with specific environmental conditions like water and oxygen, leads to the creation of malachite, making these areas rich sources of the gemstone.
UNITED STATES
In the southwestern U.S., particularly in Arizona, malachite is found in association with copper mines. The mineral here forms in arid climates where evaporation rates are high, facilitating the precipitation of copper minerals.
RUSSIA
The Ural Mountains in Russia have historically been a significant source of malachite. The malachite found here often displays a very deep, almost velvety green colour and has been used extensively in Russian decorative arts.
Chemical Composition & Colouring of Malachite
The chemical formula for malachite, Cu₂CO₃(OH)₂, shows it contains two copper (Cu) atoms, one carbonate group (CO₃), and two hydroxide groups (OH). Copper is crucial for malachite's formation and its vibrant green colour. In malachite, copper is in a +2 oxidation state, which allows it to form a stable structure with carbonate and hydroxide, giving the mineral its chemical stability and distinct colour.
The green colour of malachite results from how light interacts with the copper ions. These ions absorb most wavelengths of light but reflect green, which is why we see this colour. The specific arrangement of copper with carbonate and hydroxide in malachite's crystal lattice also influences the intensity and shade of green.
Think about the Statue of Liberty which is made of copper. It appears green because of how oxygen has interacted with the copper (oxidation) over time.
Malachite's colour can vary from light green to a dark, almost blackish-green, based on the copper concentration and the presence of other trace elements or impurities during its formation. For instance, higher copper content typically leads to a darker green, while impurities or inter-growths with minerals like azurite (which is blue) can change its appearance and colour.
DID YOU KNOW?
Malachite is idiochromatic which refers to minerals that have a characteristic and inherent colour due to their chemical composition – meaning the mineral's colour is a direct result of the elements that make up the mineral itself, rather than impurities or defects in the crystal structure. This means you won’t find malachite in any other colour other than green!
Identification Of malachite
SUGGESTED TESTING METHODS
We recommend using the following standard gemmological tools and methods to determine authenticity:
OBSERVATION
Look for the intense green colour and unique banding pattern are strong indicators of malachite. It should have a vitreous to sub-vitreous lustre on fresh surfaces. Malachite is renowned for its vibrant green colour and unique banded patterns, which are usually concentric or radial. It can grow as prismatic crystals but this is very rare. It typically presents in a few common forms:
SPECIFIC GRAVITY
The specific gravity of malachite typically falls between 3.6 and 4.0, which is higher than many other green minerals. This density is indicative of its high copper content.
HEFT
Malachite is a copper-based mineral and therefore will feel heavier when you pick it up and drop a piece into your hand, especially compared to artificial malachite that is made from polymer clay.
DESTRUCTIVE TESTING
Destructive testing refers to methods that evaluate a gemstone's properties, authenticity, and treatments by causing irreversible damage to the sample. Destructive testing is not recommended and should only be carried out as a last resort. Do not conduct destructive testing on valuable items, items that you don’t own or without the owner’s permission to do so.
Hardness Test: Malachite can be scratched by items like a copper penny or a pocket knife, confirming its hardness of 3.5 to 4 on the Mohs scale.
Streak Test: Malachite produces a light green streak when rubbed against a streak plate. This is distinctive and helps differentiate it from other minerals, which may have different streak colours.
Malachite Gallery
Similar materials to Malachite
MALACHITE AND CHRYSOCOLLA
Malachite often forms alongside chrysocolla, a blue to blue-green copper mineral. This occurs in the oxidised zones of copper deposits, where the two minerals grow together or in layers. The mix of green malachite and blue chrysocolla creates beautiful specimens that are highly valued by collectors. Chrysocolla typically forms in porous rocks, allowing malachite to fill in and create patterns alongside chrysocolla's own shapes. This combination not only looks attractive but also shows the complex chemical processes in copper-rich areas.
MALACHITE AND AZURITE
Malachite and azurite frequently appear together because they have similar chemical compositions, both being copper carbonate minerals. Azurite, with its deep blue colour, can change into green malachite over time through a process called pseudomorphism, where the shape of azurite remains but the material becomes malachite. This results in interesting specimens showing both blue and green colours. They can also grow side by side, forming banded or layered patterns. These combinations are often found in the upper parts of copper ore deposits, where changes in the environment cause azurite to transform into malachite, demonstrating the dynamic nature of mineral formation.
Enhancements & Artificial Malachite
SYNTHETIC
Synthetic malachite exists but is relatively rare in the market compared to natural specimens. Synthetic means that it has essentially same chemical composition as it’s natural counterpart. These were predominantly produced in the then USSR in the 80s but its unknown to date how much of this may be in the jewellery market.
ARTIFICIAL AND IMITATION MATERIALS
There is much artificial malachite on the market particularly for pendants and carvings. This is typically made from a polymer clay. This can be easily spotted as it contains black - malachite is never truly black but rather a very dark green. It also has only two or three shades of green. Natural malachite has varying bands of different greens. Clay will also feel much lighter than malachite as it does not contain copper.
Malachite buying guide
HIGHER QUALITY
Lustre: Bright vitreous or silky lustre depending on the habit.
Colour and Banding: Look for various green colours that are typically banded in varying widths.
Condition: Ideally look for intact crystals with minimal chips, no scratches and broken pieces.
LOWER QUALITY
Lustre: Dull or lacklustre appearance. Surfaces that do not reflect light well.
Colour and Banding: Limited to three or four colours including black, jagged edge banding which suggests polymer clay.
Condition: Avoid excessively broken, scratched, chipped, or damaged crystals.